华南师范大学环境学院

科学研究

环境功能材料与污染控制团队

2019-12-17 20:47:00 来源:华南师范大学环境学院 点击:

团队名称:环境功能材料与污染控制

 

团队负责人:李来胜 教授

 

团队成员:

(1)教授/研究员:李来胜、舒月红

(2)副教授/副研究员:王熙、邓达义、廖高祖、王静、唐一鸣

 

团队简介:

环境功能材料团队现有成员8名,其中有2名正高、6名副高。团队拥有广东省饮用水安全保障工程技术研究中心、广东省环境功能材料重点实验室等省部级科研平台,主要从事环境功能材料(碳材料,M41s和SBA系列硅基分子筛以及PVDF膜等)的研制及其在吸附、环境催化和分离等方面应用研究,以及土壤修复技术等研究。团队具备完善的科研条件,已到位的高质量科研仪器和设备包括气相色谱-质谱联用仪、气相色谱仪、总有机碳分析仪、高效液相色谱、电化学滴定仪、电化学工作站、紫外可见近红外漫反射光谱仪等。团队近年承担多项国家自然科学基金、国家高技术研究发展计划(863计划)、国家重大科技专项水专项和国家环保公益性行业科研专项子课题等国家级纵向项目等科研项目。在Environmental Science & Technology, Applied Catalysis B: Environmental, Water Research, Angewandte Chemie International Edition, Journal of Materials Chemistry A, ACS Applied Materials & Interfaces, Journal of Hazardous Materials, Chemical Engineering Journal等刊物上发表论文100余篇,申请发明专利10项。

 

研究方向:

团队主要围绕纳米功能材料的设计、合成和性能及其在环境修复和新能源技术等方面开展相关研究工作,现有以下方向:

(1) 环境功能材料:M41S,SBA和CMK等介孔材料;过渡金属氧化物、硫化物及其复合材料;二维过渡金属碳化物或氮化物(MXene)

(2) 高级氧化技术:催化臭氧氧化技术;光催化/光电催化技术;过硫酸盐活化技术;

(3) 环境修复:难降解、有毒和持久性有机污染物控制;水污染控制技术及水体修复;土壤修复技术;清洁生产、生态规划及循环经济

(4) 新能源技术:太阳能的有效利用;电催化分解水制取氢能;光-热/光-电协同催化产氢。

 

代表性成果:

(1) 重要科研项目

在研

[1] F调控Fe-M41S分子筛疏水性界面强化催化臭氧氧化去除水中抗生素机制,国家自然科学基金项目(51978288),202001-202312,负责人:李来胜

[2] MXene二维材料的界面调控及其光催化-臭氧氧化协同降解PPCPs,国家自然科学基金面上项目(22076050),202101-202412,负责人:王静

[3] 新型二维过渡金属碳化物(MXene)复合材料高效光催化制氢的研究,广东省基础与应用基础研究基金青年项目(2019A1515110945),202001-202212,负责人:王静

[4] 脉冲电镀法构筑晶面耦合型钒酸铋复合薄膜电极及光电催化降解四环素研究, 国家自然科学基金青年项目(52000079), 202101-202312, 负责人:唐一鸣

[5] 钒酸铋复合薄膜电极光电催化降解四环素研究, 广州市科技计划基础与应用基础研究项目 (202102020355), 202101 - 202312,负责人:唐一鸣

[6] 太滆运河农业复合污染控制与清洁流域技术集成与应用,国家重大科技专项-子课题(2017ZX07202004),201701-202006,负责人:李来胜

[7] 非均相催化臭氧氧化催化剂活性组分溶出问题研究,国家自然科学基金项目(21247004),201301-201312,负责人:李来胜

[8] 环境中高关注有机化学品的污染控制技术,国家高技术研究发展计划-863计划-子课题(2013AA062705),201201-201512,负责人:李来胜

[9] 滨江城镇集中工业园排水自然回归成套技术研究与工程示范,国家十二五重大水专项-子课题(2012ZX07206003),201201-201512,负责人:李来胜

[10] 大气氮磷沉降对典型河口与湖库水生态环境的影响评价,国家环保公益性行业科研专项-子课题(201109008),201101-201312,负责人:李来胜

[11] 稀土元素掺杂Ti改性MCM-41介孔分子筛催化臭氧氧化水中有机污染物的研究,国家自然科学基金项目(20977036),201001-201212,负责人:李来胜

[12] 脉冲电镀法构筑晶面耦合型复合薄膜电极及光电催化降解阿莫西林研究, 广东省自然科学基金面上项目 (2019A1515012202), 201901 - 202112, 负责人:唐一鸣

[13] 表面活性剂强化活化过硫酸钠原位修复典型POPs污染场地的机理和调控机制研究, 国家自然科学基金项目(41201304),201201-201512,负责人:邓达义

[14] 矿物对土壤吸附疏水性有机污染物的调控作用,国家自然科学基金项目(21347003),201301-201412,负责人:舒月红

[15] 磁性离子交换树脂吸附-强化混凝去除消毒副产物前驱物的机理研究,国家自然科学基金项目(51308033),201301-201612,负责人:曹百川

[16] Z型三元光催化电解池与微生物电解池联用产氢及处理难降解有机物,国家自然科学基金项目(51308230),201301-201612,负责人:王熙

[17] 石墨烯异质结增强光催化/臭氧耦合水处理技术的性能及机制研究,国家自然科学基金项目(21207042),201201-201512,负责人:廖高祖

 

(2)代表性高水平论文

[1] Tan YS, Chen WR*, Liao GZ, Li XK, Wang J, Tang YM, Li LS* (2022) Strategy for improving photocatalytic ozonation activity of g-C3N4 by halogen doping for water purification, Applied Catalysis B: Environmental, 306, 121133

[2] Chen ZS, Chen WR*, Liao GZ, Li XK, Wang J, Tang YM, Li LS* (2022) Flexible construct of N vacancies and hydrophobic sites on g-C3N4 by F doping and their contribution to PFOA degradation in photocatalytic ozonation, Journal of Hazardous Materials, 428, 128222

[3] Liao GZ*, Xu P, Lu P, Qing XJ, Yu ZJ, Chang Y*, Chen WR*, Tang YM, Wang J, Wang X, Li XK, Li LS, Xia DH (2022) Dramatic enhancement of mineralization capability for ozone/peroxymonosulfate process by single atom Co/CMK-3 catalyst, Separation and Purification Technology, 287, 120582

[4] Liao GZ*, Qing XJ, Xu P, Li LS, Lu P, Chen WR*, Xia DH (2022) Synthesis of single atom cobalt dispersed on 2D carbon nanoplate and degradation of acetaminophen by peroxymonosulfate activation, Chemical Engineering Journal, 427,132027

[5] Chen WR, He HX, Zou RN, Chen YD, Li XK, Wang J*, Tang YM, Li LS* (2021) Unravelling the facets-dependent behavior among H2O2, O3 and oxygen vacancies on CeOx and the promotion of peroxone reaction at acidic condition, Environmental Science: Nano, 8, 3138-3152

[6] Chen WR, Xie JX, Li XK*, Li LS* (2021) Oxygen vacancies and Lewis sites activating O3/H2O2 at wide pH range via surface electron transfer over CeOx@SiO2 for nitrobenzene mineralization, Journal of Hazardous Materials, 406, 124766

[7] Xie JX, Chen WR*, Lv YF, Chen HY, Li XK, Li LS* (2021) Synthesis of CeOx@SiO2 with tandem effect of mass transfer and activation for enhancing sulfanilamide degradation with ozone, Separation and Purification Technology, 256, 117823

[8] Xu DX, Li ZD, Li LS*, Wang J* (2020) Insights into the Photothermal Conversion of 2D MXeneNanomaterials: Synthesis, Mechanism, and Applications, Advanced Functional Materials, 30, 2000712

[9] Li SY, Wang J*, Ye YY, Tang YM, Li XK, Gu FL, Li LS* (2020) Composite Si-O-metal network catalysts with uneven electron distribution: Enhanced activity and electron transfer for catalytic ozonation of carbamazepine, Applied Catalysis B-Environmental, 263, 118311

[10] Chen WR, Bao YX, Li XK, Huang J*, Xie JX, Li LS* (2020) Role of SiF groups in enhancing interfacial reaction of Fe-MCM-41 for pollutant removal with ozone, Journal of Hazardous Materials 393, 122387

[11] Wang L, Wu HH, Deng DY* (2020) Role of surfactants in accelerating or retarding persulfate decomposition, Chemical Engineering Journal, 384, 123303 

[12] Liu JG, Jiang SJ, Chen DD, Dai GL, Wei DY, Shu YH* (2020) Activation of persulfate with biochar for degradation of bisphenol A in soil, Chemical Engineering Journal, 381,122637

[13] Xie JX, Li XK, Chen WR*, Sun XL, Chen KX, Tang YM, Li LS* (2020) Enhanced mineralization of oxalate by heterogeneous peroxone: The interfacial reaction on the core-shell CeOx@SiO2, Chemical Engineering Journal, 379, 122344

[14] Li SY, Li XK*, Wu HT, Sun XL, Gu FL, Zhang LM, He H, Li LS* (2019) Mechanism of Synergistic Effect on Electron Transfer over Co–Ce/MCM-48 during Ozonation of Pharmaceuticals in Water, ACS Applied Materials & Interfaces, 11, 23957-23971

[15] Tang YM*, Zheng ZX, Sun XL, Li XK, Li LS* (2019) Ternary CdS-MoS2 coated ZnO nanobrush photoelectrode for one-dimensional acceleration of charge separation upon visible light illumination, Chemical Engineering Journal, 368, 448-458

[16] Chen WR, Li XK, Tang YM*, Zhou JL, Wu D, Li LS* (2018) Mechanism insight of pollutant degradation and bromate inhibition by Fe-Cu-MCM-41 catalyzed ozonation. Journal of Hazardous Materials, 346, 226-233

[17] Wang L, Peng LB, Xie LL, Deng PY, Deng DY* (2017) Compatibility of Surfactants and Thermally Activated Persulfate for Enhanced Subsurface Remediation, Environmental Science & Technology, 12, 7055-7064

[18] Hu Z, Wang X*, Dong HT, Li SY, Li XK, Li LS* (2017) Efficient photocatalytic degradation of tetrabromodiphenyl ethers and simultaneous hydrogen productionby TiO2-Cu2O composite films in N2 atmosphere: Influencing factors, kineticsand mechanism, Journal of Hazardous Materials, 340, 1-15

[19] Wang J, Zhu LL, Dharan G and Ho GW (2017) Electrodeposited cobalt phosphide superstructures for solar-driven thermoelectrocatalytic overall water splitting, Journal of Materials Chemistry A, 5, 16580-16584. (Themed collection of 2017 JMCA hot papers)

[20] Chen WR, Li XK, Pan ZQ, Ma SS, Li LS* (2016) Effective mineralization of Diclofenac by catalytic ozonation using Fe-MCM-41 catalyst. Chemical Engineering Journal, 304,594-601.

[21] Huang JY, Wang X, Pan ZQ, Li XK, Ling Y, Li LS* (2016) Efficient degradation of perfluorooctanoic acid (PFOA) by photocatalytic ozonation. Chemical Engineering Journal, 296, 329-334

[22] Peng LB, Wang L, Hu XT, Wu PH, Wang XQ, Huang CM, Wang XY, Deng DY* (2016) Ultrasound assisted, thermally activated persulfate oxidation of coal tar DNAPLs, Journal of Hazardous Materials, 318, 497-506

[23] Wang J, Tan CF, Zhu T, Ho GW (2016), Topotactic consolidation of monocrystalline CoZn hydroxides for advanced oxygen evolution electrodes, Angewandte Chemie International Edition, 128, 10482-10486

[24] Lan BY, Wang YX, Wang X, Zhou XT, Kang Y, Li LS* (2016) Aqueous arsenic (As) and antimony (Sb) removal by potassium ferrate. Chemical Engineering Journal, 29, 389-397

[25] Sun QQ, Wang Y, Li SS*, Bing JS, Wang YX, Yan HH (2015) Mechanism for enhanced degradation of clofibric acid in aqueous by catalytic ozonation over MnOx/SBA-15. Journal of Hazardous Materials, 286, 276-284

[26] Tang YM, Wang P, Rose Amal*, Yun Hau Ng* (2015) Frequency-regulated pulsed electrodeposition of CuInS2 on ZnO nanorod arrays as visible light photoanodes, Journal of Materials Chemistry A, 3, 15876–15881

[27] Wang J and Ghim Wei Ho (2015) Corrosion-mediated self-assembly (CMSA): direct writing towards sculpturing of 3D tunable functional nanostructures, Angewandte Chemie International Edition, 127, 16030-16034

[28] Tang YM, Traveerungroj P, Tan HL, Wang P, Rose Amal*, Yun Hau Ng* (2015) Scaffolding an ultrathin CdS layer on a ZnO nanorod array using pulsed electrodeposition for improved photocharge transport under visible light illumination, Journal of Materials Chemistry A, 3,19582-19587

[29] Chen WR, Li XK, Pan ZQ, Bao YX, Ma SS, Li LS* (2015) Efficient adsorption of Norfloxacin by Fe-MCM-41 molecular sieves: Kinetic, isotherm and thermodynamic studies. Chemical Engineering Journal, 281, 397-403

[30] Bao YX, Yan XM, Du W, Xie XN, Pan ZQ, Zhou JL, Li LS* (2015) Application of amine-functionalized MCM-41 modified ultrafiltration membrane to remove chromium (VI) and copper (II). Chemical Engineering Journal, 28, 460-467

[31] Deng DY, Lin XT, Ou JM, Wang Z, Li ST, Deng ML, Shu YH (2015) Efficient chemical oxidation of high levels of soil-sorbed phenanthrene by ultrasound induced, thermally activated persulfate, Chemical Engineering Journal, 265,176-183

[32] Liao GZ, Zhu ZY, Li LS*, Lan BY (2014) Enhanced photocatalytic ozonation of organics by g-C3N4 under visible light irradiation, Journal of Hazardous Materials, 28, 531-535

[33] Sun QQ, Li LS*, Yan HH (2014) Influence of the surface hydroxyl groups of MnOx/SBA-15 on heterogeneous catalytic ozonation of oxalic acid. Chemical Engineering Journal, 242, 348–356

[34] Wang Z, Deng DY*, Yang LL (2014) Degradation of dimethyl phthalate in solutions and soil slurries by persulfate at ambient temperature, Journal of Hazardous Materials, 271, 202-209

[35] Deng DY, Peng LB, Guan MY, Kang Y (2014) Impact of activation methods on persulfate oxidation of methyl tert-butyl ether, Journal of Hazardous Materials, 264, 521-528

[36] Lan BY, Huang RH, Li LS*, Yan HH (2013) Catalytic ozonation of p-chlorobenzoic acid in aqueous solution using Fe-MCM-41 as catalyst. Chemical Engineering Journal, 219, 346–354

[37] Bing JS, Li LS*, Lan BY, Liao GZ (2012) Synthesis of cerium-doped MCM-41 for ozonation of p-chlorobenzoic acid in aqueous solution. Applied Catalysis B: Environmental, 115-116, 16-24

[38] Wang J, Wang CF and Chen S (2012) Amphiphilic egg-derived carbon dots: rapid plasma fabrication, pyrolysis process and multicolor printing patterns, Angewandte Chemie International Edition, 124, 9431-9435.

[39] Huang RH, Lan BY, Li LS*, Catalytic ozonation of p-chlorobenzoic acid over MCM-41 and Fe loaded MCM-41. Chemical Engineering Journal, 18 (2012) 19-24

[40] Huang RH, Li LS*, Yan HH (2011) Catalytic activity of Fe/SBA-15 for ozonation of dimethyl phthalate in aqueous solution. Applied Catalysis B: Environmental, 106, 264-271

[41] Cao BC, Baoyu Gao BY, Liu X, Wang MM, Yang ZL, Yue QY (2011) The impact of pH on floc structure characteristic of polyferric chloride in a low DOC and high alkalinity surface water treatment, Water Research, 45, 6181-6188

[42] Jing Y, Li LS*, Zhang QY (2011) Photocatalytic ozonation of dimethyl phthalate with TiO2 prepared by a hydrothermal method. Journal of Hazardous Materials, 189, 40-47

[43] Shu YH, Li LS*, Zhang QY, Wu HH (2010) Equilibrium, kinetics and thermodynamic studies for sorption of chlorobenzenes on CTMAB modified bentonite and kaolinite. Journal of Hazardous Materials, 173, 47-53.

[44] Li LS*, Ye WY, Zhang QY, Sun FQ, Lu P, Li XK (2009) Catalytic ozonation of dimethyl phthalate over cerium supported on activated carbon. Journal of Hazardous Materials, 170, 411-416

[45] Li XK, Zhang QY, Tang LL, Lu P, Sun FQ, Li LS* (2009) Catalytic ozonation of p-chlorobenzoic acid by activated carbon and nickel supported activated carbon prepared from petroleum coke, Journal of Hazardous Materials, 163, 115-120.

 

(3)授权发明专利或成果转化、成果应用

[1] 一种Fe2O3-CuO@SiO2核壳式催化剂及其制备方法和应用,中国发明专利,专利授权号:ZL201810076436.7

[2] 用于臭氧氧化的高稳定性过渡金属改性SBA-15催化剂的制备方法,中国发明专利,专利授权号:ZL201310285121.0.

[3] 控释型高铁酸钾复合体及其制备和应用,中国发明专利,专利授权号:ZL201410118066.0

[4] 一种Co-Mn-MCM-41分子筛的制备方法及其应用,中国发明专利,专利申请号:2015111300481450

 

(4)其它重要成果

TiO2-based heterogeneous catalysis for photocatalytic hydrogen generation and photodegradation, Encyclopedia of Inorganic and Bioinorganic Chemistry, Wiley publisher, 2016 (章节著作)

 

团队联系人:陈伟锐,

联系电话:13560206247

电子邮箱:chen_2019@m.scnu.edu.cn/cwr_56@163.com